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Light-mediated photomultiplication via cyclic energy transfer in organic layers

Journal
Advanced Functional Materials
Date
2025.01.29
Abstract

Photomultiplication organic photodetectors (PM-OPDs) demonstrate exceptional sensitivity in low-light environments, making them valuable for imaging, environmental monitoring, and wearable health sensors. However, traditional PM-OPDs require significantly high operational voltages, which lead to elevated dark current and degrade sensitivity and noise performance. To address these limitations, we introduce a novel light-mediated PM-OPD that enhances signal gain through a cycle of light emission and reabsorption within the active layers. This design integrates emission and absorption layers, achieving an external quantum efficiency exceeding 200% while maintaining a low dark current (~10?? A/cm²) and high detectivity over 5×10¹³ Jones. By reabsorbing internally generated light to drive photomultiplication, the device enables efficient amplification without noise penalties. It achieves a 29.5 dB gain in photoplethysmography (PPG) signal detection at 10 lux and demonstrates scalability for cost-effective production using thermal evaporation, making it a promising solution for low-power, high-sensitivity wearable sensors.

Reference
Adv. Funct. Mater. 2423993 (2025)
DOI
https://doi.org/10.1002/adfm.202423993